Never figured this one out.
A datetime index in a dataframe is selected by df.loc['2022-07-18 15:15:00'] or iloc or whatever but how can I perform a conditional check on the time in an datetime to create a column value for a specific time? i.e.
if index.time = '***16:00:00':
df['end'] = True
I don't know how to use wildcards in this instance either.

