I just figured a strange behavior in the Toolset's Type-Access plugin. I think this si the same case as this unresolved issue. I my case, it's a multisite context, so users can exists in others sites, specially super-admins.
Logged as super-admin, when Type-Access is active, the user-list of a blog is empty, so is the role list when I want to add a new user.
Strangely, in cli (wp role list, wp user list) -mode, users and roles are well shown.