I'm not sure if it's even possible. According to the docs, add-on options can be specified in app.json: https://devcenter.heroku.com/articles/app-json-schema#addons
I tried the following json, and it provisions the scheduler add-on, but without any jobs defined.
"addons": [
{
"plan": "scheduler",
"options": {
"command": "my command",
"dyno-size": "Free",
"every": 10,
"at": 0
}
}
]