It's an alternative syntax for declaring static arrays, but there are some key details to understanding the differences in syntax between them.
@() is the array sub-expression operator. This works similarly to the group-expression operator () or sub-expression operator $() but forces whatever is returned to be an array, even if only 0 or 1 element is returned. This can be used inline wherever an array or collection type is expected. For more information on these operators, read up on the Special Operators in the documentation for PowerShell.
The 1, 2, 3, 4 is the list-expression syntax, and can be used anywhere an array is expected. It is functionally equivalent to @(1, 2, 3, 4) but with some differences in behavior than the array subexpression operator.
@( Invoke-SomeCmdletOrExpression ) will force the returned value to be an array, even if the expression returns only 0 or 1 element.
# Array sub-expression
$myArray = @( Get-Process msedge )
Note this doesn't have to be a single cmdlet call, it can be any expression, utilizing the pipeline how you see fit. For example:
# We have an array of fruit
$fruit = 'apple', 'banana', 'apricot', 'cherry', 'a tomato ;)'
# Fruit starting with A
$fruitStartingWithA = @( $fruit | Where-Object { $_ -match '^a' } )
$fruitStartingWithA should return the following:
apple
apricot
a tomato ;)
There's another way to force an array type and I see it often mentioned on Stack Overflow as a cool trick (which it is), but with little context around its behavior.
You can use a quirk of the list-expression syntax to force an array type, but there are two key differences between this and using the array sub-expression operator. Prefixing an expression or variable with a comma , will force an array to be returned, but the behavior changes between the two. Consider the following example:
# Essentially the same as @( $someVar )
$myArray1 = , $someVar
# This behaves differently, read below
$myArray2 = , ( Invoke-SomeCmdletOrExpression )
@() or prefixing a variable with , will flatten (another word often used here is unroll) the resulting elements into a single array. But with an expression you have to use the group-expression operator if you use the comma-prefix trick. Due to how the grouped expression is interpreted you will end up with an array consisting of one element.
It will not flatten any resulting elements in this case.
Consider the Get-Process example above. If you have three msedge processes running, $myArray.Count will show a count of 3, and you can access the individual processes using the array-index accessor $myArray[$i]. But if you do the same with $myArray2 in the second list-expression example above, $myArray2.Count will return a count of 1. This is essentially now a multi-dimensional array with a single element. To get the individual processes, you would now need to do $myArray2[0].Count to get the process count, and use the array-index accessor twice to get an individual process:
$myArray2 = , ( Get-Process msedge )
$myArray2.Count # ======> 1
# I have 32 Edge processes right now
$myArray2[0].Count # ===> 32
# Get only the first msedge process
$myArray[0][0] # =======> Handles NPM(K) PM(K) WS(K) CPU(s) Id SI ProcessName
# =======> ------- ------ ----- ----- ------ -- -- -----------
# =======> 430 19 101216 138968 74.52 3500 1 msedge
This can be unclear at first because printing $myArray2 to the output stream will show the same output result as $myArray from the first example, and $myArray1 in the second example.
In short, you want to avoid using the comma-prefix trick when you want to use an expression, and instead use the array sub-expression @() operator as this is what it is intended for.
Note: There will be times when you want to define a static array of arrays but you will be using list-expression syntax anyways, so the comma-prefix becomes redundant. The only counterpoint here is if you want to create an array with an array in the first element to add more arrays to it later, but you should be using a generic List[T] or an ArrayList instead of relying on one of the concatenation operators to expand an existing array (+ or += are almost always bad ideas on non-numeric types).
Here is some more information about arrays in PowerShell, as well as the Arrays specification for PowerShell itself.