There are infinitely many choices for n0 and c that can be used to prove this bound holds. We need to find n0 and c such that for n >= n0, f(n) <= c * g(n). In your case, we need 100n + 5 <= cn^2. We can rearrange this as follows using basic algebra:
cn^2 - 100n - 5 >= 0
We can use the quadratic formula to find the roots:
n1, n2 = [100 +- sqrt(10000 + 20c)]/2c
Because c is positive we know the sqrt term will be greater than 100 once evaluated and since we are only interested in n > 0 we can discard the smaller of these solutions and focus on this:
n0 = [100 + sqrt(10000 + 20c)]/2c
We can simplify this a bit:
n0 = [100 + sqrt(10000 + 20c)]/2c
= [100 + 2*sqrt(2500 + 5c)]/2c
= [50 + sqrt(2500 + 5c)]/c
At this point, we can choose either a value for c or a value for n0, and solve for the other one. Your example chooses c = 4 and gets the approximate answer n0 ~ 25.05. If we'd prefer to choose n0 directly (say we want n0 = 10) then we calculate as follows:
10 = [50 + sqrt(2500 + 5c)]/c
10c = 50 + sqrt(2500 + 5c)
(10c - 50) = sqrt(2500 + 5c)
(100c^2 - 1000c + 2500) = (2500 + 5c)
100c^2 - 1005c = 0
c(100c - 1005) = 0
c = 0 or c = 1005/100 ~ 10.05
Because the solution c=0 is obviously no good, the solution c ~ 10.05 appears to work for our choice of n0 = 10. You can choose other n0 or c and find the corresponding constant in this way.