Why do I need to link against opengl32 when I have glew32?

You do not (always) need both the libopengl32.dll and the libglew32 libraries when compiling an OpenGL program. You need both when compiling a GLEW program (which implies also being an OpenGL program since GLEW builds upon OpenGL). For some people, this difference is academic since they would never consider writing an OpenGL program without the convenience of GLEW (et al.). However, GLEW is not required by OpenGL.

Your OpenGL library is the base upon which your GLEW library depends. You can use OpenGL without GLEW, but you cannot use GLEW without OpenGL. If your program uses GLEW, then you need to link your GLEW library because you are using it, and you need to link your OpenGL library because GLEW (and probably your code as well) uses that. If you are using pure OpenGL with no elements of GLEW, you need just to link your OpenGL library.