Your code is a bit unusual for prolog but (with the exception of prime(1)) it works.
Here is a solution for your predicate:
nextprime(N,N):-
prime(N),
!.
nextprime(P, Prime):-
PP is P+1,
nextprime(PP,Prime).
nthprime(1, 2).
nthprime(N, Prime):-
N>1,
NN is N-1,
nthprime(NN, PrevPrime),
PP is PrevPrime+1,
nextprime(PP, Prime).
?- nthprime(1,P).
P = 2 ;
false.
?- nthprime(2,P).
P = 3 ;
false.
?- nthprime(3,P).
P = 5 ;
false.
It works as follows: It is known that the first prime number is 2 (nthprime(1, 2).). For every other number N larger than 1, get the previous prime number (nthprime(NN, PrevPrime)), add 1 until you hit a prime number. The add 1 part is done through a help predicate nextprime/2: for a given number P it will check if this number is a prime. If yes, it returns this number, otherwise it will call itself for the next higher number (nextprime(PP,Prime)) and forwards the output. The bang ! is called a cut which cuts the other choice branches. So if you once hit a prime, you can not go back and try the other path.
To test it you can ask ?- nthprime(N,P). for a given N. Or to check multiple answers at once, let's introdice a helperpredicate nthprimeList/2 which calls nthprime/2 for every item in the firstlist and puts the "output" into a list:
nthprimeList([],[]).
nthprimeList([N|TN],[P|TP]):-
nthprime(N,P),
nthprimeList(TN,TP).
?- nthprimeList([1,2,3,4,5,6,7,8,9],[P1,P2,P3,P4,P5,P6,P7,P8,P9]).
P1 = 2,
P2 = 3,
P3 = 5,
P4 = 7,
P5 = 11,
P6 = 13,
P7 = 17,
P8 = 19,
P9 = 23;
false.