In C (as in, defined by the language standard), no, there is no way.
There are however compiler-specific ways using which you can get really close to achieving what you want. The most famous, as @Nate Eldredge notes in the comments, is the builtin function __builtin_constant_p() available in GCC and Clang.
Here's the relevant excerpt from the GCC doc:
Built-in Function: int __builtin_constant_p (exp)
You can use the built-in function __builtin_constant_p to determine if a value is known to be constant at compile time and hence that GCC can perform constant-folding on expressions involving that value. The argument of the function is the value to test. The function returns the integer 1 if the argument is known to be a compile-time constant and 0 if it is not known to be a compile-time constant. A return of 0 does not indicate that the value is not a constant, but merely that GCC cannot prove it is a constant with the specified value of the -O option.
Note that this function does not guarantee to detect all compile-time constants, but only the ones that GCC is able to prove as such. Different optimization levels might change the result returned by this function.
This built-in function is widely used in glibc for optimization purposes (example), and usually the result is only trusted when it's 1, assuming a non-constant otherwise:
void somefunc(int x) {
if (__builtin_constant_p(x)) {
// Perform optimized operation knowing x is a compile-time constant.
} else {
// Assume x is not a compile-time constant.
}
}
Using your own example:
const double a = 2.0;
const double b = 3.0;
double c1 = a / b; // done at compile time (constant folding / propagation)
double c2 = *(volatile double*)&a / *(volatile double*)&b; // done at run time
assert(__builtin_constant_p(c1));
assert(!__builtin_constant_p(c2));