The front-end SiteMinder web agent is the guaranty that the session is valid - you must make sure via server/network configuration that your application cannot be accessed directly without first passing through the SiteMinder web agent.
Also, SiteMinder asserts multiple headers. SM_USER should not be used alone because it can be asserted by the web agent in some circumstances when the user does not actually have a valid session. Instead, you should first look for the existence (non-blank) of SM_SERVERSESSIONID, which only exists if the session is valid.
Lastly, I generally try to avoid SM_USER at all - because SM_USER is actually not a user attribute at all, but rather is "the login identifier used for authentication". If SiteMinder authenticates users via federation (e.g. SAML) or x509 authentication, SM_USER will be rather different than if a login form was used. Instead, its better in SiteMinder to set a "universal id" that is a user attribute, and appears in the headers as SM_UNIVERSALID. Your SiteMinder administrators will know how to do this (and may already have - look to see if you have a SM_UNIVERSALID header available already).
One other caution, in some SiteMinder configurations, the underscore will not be in the header name (use of the underscore is called "legacy" header mode in SiteMinder), so you might want to make your app configurable with respect to the header names, e.g. SMSERVERSESSIONID, SMUSER, SMUNIVERSALID etc.
If you want to programmatically re-validate a session, you can use the SiteMinder Agent API or REST API, or look at my company's product "SSO/Rest" which provides a comprehensive set of uniform REST interfaces to SiteMinder and also other SSO providers (http://www.idfconnect.com).
HTH!
-Richard