I have a data set that has some instances where for a given location at the same date and time the value is different. I am trying to create a subset data frame showing these instances. This is an example of what I mean:

I have looked at similar questions on SO but I can't seem to get what I want. I keep getting back instances where this isn't the case.
Here's the code I am using:
dat1<-data_concern_join2%>%
group_by(locid,stdate,sttime,charnam,valunit)%>%
filter(n()>1)
Sample Data:
structure(list(orgid = c("USGS-NJ", "USGS-NJ", "USGS-NJ", "USGS-NJ",
"USGS-NJ", "USGS-NJ", "USGS-NJ", "USGS-NJ", "USGS-NJ", "USGS-NJ",
"USGS-NJ", "USGS-NJ", "USGS-NJ", "USGS-NJ", "USGS-NJ"), locid = c("USGS-01396030",
"USGS-01396030", "USGS-01389850", "USGS-01389850", "USGS-01391500",
"USGS-01391500", "USGS-01391500", "USGS-01391500", "USGS-01393960",
"USGS-01390610", "USGS-01391500", "USGS-01390610", "USGS-01391500",
"USGS-01378760", "USGS-01378760"), stdate = structure(c(11359,
11359, 11359, 11359, 16504, 16504, 16112, 16112, 11367, 13860,
12401, 13860, 16325, 13006, 13006), class = "Date"), sttime = structure(c(34200,
34200, 36000, 36000, 40500, 40500, 39600, 39600, 36000, 39600,
32400, 39600, 38400, 36900, 36900), class = c("hms", "difftime"
), units = "secs"), charnam = c("Specific conductance", "Specific conductance",
"Specific conductance", "Specific conductance", "Specific conductance",
"Specific conductance", "Specific conductance", "Specific conductance",
"Specific conductance", "Specific conductance", "Specific conductance",
"Specific conductance", "Specific conductance", "Specific conductance",
"Specific conductance"), val = c(7450, 7300, 3210, 3180, 1930,
1920, 1740, 1650, 1480, 1390, 1380, 1330, 1300, 1280, 1270),
valunit = c("uS/cm @25C", "uS/cm @25C", "uS/cm @25C", "uS/cm @25C",
"uS/cm @25C", "uS/cm @25C", "uS/cm @25C", "uS/cm @25C", "uS/cm @25C",
"uS/cm @25C", "uS/cm @25C", "uS/cm @25C", "uS/cm @25C", "uS/cm @25C",
"uS/cm @25C"), swqs = c("FW2-NT", "FW2-NT", "FW2-NT", "FW2-NT",
"FW2-NT", "FW2-NT", "FW2-NT", "FW2-NT", "FW2-NT", "FW2-NT",
"FW2-NT", "FW2-NT", "FW2-NT", "FW2-NT", "FW2-NT"), WMA = c(7L,
7L, 4L, 4L, 4L, 4L, 4L, 4L, 7L, 4L, 4L, 4L, 4L, 6L, 6L),
year = c(2001L, 2001L, 2001L, 2001L, 2015L, 2015L, 2014L,
2014L, 2001L, 2007L, 2003L, 2007L, 2014L, 2005L, 2005L),
HUC14 = c("HUC02030104050090", "HUC02030104050090", "HUC02030103120050",
"HUC02030103120050", "HUC02030103140070", "HUC02030103140070",
"HUC02030103140070", "HUC02030103140070", "HUC02030104050010",
"HUC02030103140010", "HUC02030103140070", "HUC02030103140010",
"HUC02030103140070", "HUC02030103010040", "HUC02030103010040"
)), .Names = c("orgid", "locid", "stdate", "sttime", "charnam",
"val", "valunit", "swqs", "WMA", "year", "HUC14"), row.names = c(NA,
-15L), class = c("grouped_df", "tbl_df", "tbl", "data.frame"), vars = c("locid",
"stdate", "sttime", "charnam", "valunit"), drop = TRUE, indices = list(
13:14, 2:3, c(9L, 11L), 10L, 6:7, 12L, 4:5, 8L, 0:1), group_sizes = c(2L,
2L, 2L, 1L, 2L, 1L, 2L, 1L, 2L), biggest_group_size = 2L, labels = structure(list(
locid = c("USGS-01378760", "USGS-01389850", "USGS-01390610",
"USGS-01391500", "USGS-01391500", "USGS-01391500", "USGS-01391500",
"USGS-01393960", "USGS-01396030"), stdate = structure(c(13006,
11359, 13860, 12401, 16112, 16325, 16504, 11367, 11359), class = "Date"),
sttime = structure(c(36900, 36000, 39600, 32400, 39600, 38400,
40500, 36000, 34200), class = c("hms", "difftime"), units = "secs"),
charnam = c("Specific conductance", "Specific conductance",
"Specific conductance", "Specific conductance", "Specific conductance",
"Specific conductance", "Specific conductance", "Specific conductance",
"Specific conductance"), valunit = c("uS/cm @25C", "uS/cm @25C",
"uS/cm @25C", "uS/cm @25C", "uS/cm @25C", "uS/cm @25C", "uS/cm @25C",
"uS/cm @25C", "uS/cm @25C")), row.names = c(NA, -9L), class = "data.frame", vars = c("locid",
"stdate", "sttime", "charnam", "valunit"), drop = TRUE, .Names = c("locid",
"stdate", "sttime", "charnam", "valunit")))