python - numpy FileNotFoundError: [Errno 2] No such file or directory

I have this code:

import os.path
import numpy as np
homedir=os.path.expanduser("~")
pathset=os.path.join(homedir,"\Documents\School Life Diary\settings.npy")
if not(os.path.exists(pathset)):
    ds={"ORE_MAX_GIORNATA":5}
    np.save(pathset, ds)

But the error that he gave me is:

FileNotFoundError: [Errno 2] No such file or directory: 'C:\\Users\\Maicol\\Documents\\School Life Diary\\settings.npy'

How can I solve this? The folder isn't created...

Thanks