When do emoji fonts work if listed after sans-serif?

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My understanding has been that sans-serif would give you the operating system default sans-serif font and that every OS would support this. In what scenario would emoji fonts listed after sans-serif be reachable?

Github 2017-08-09

font-family: -apple-system, BlinkMacSystemFont, "Segoe UI", Helvetica, Arial, sans-serif, "Apple Color Emoji", "Segoe UI Emoji", "Segoe UI Symbol"
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