How to apply function to each row of specified column of PySpark DataFrame

I have a PySpark DataFrame consists of three columns, whose structure is as below.

In[1]: df.take(1)    
Out[1]:
[Row(angle_est=-0.006815859163590619, rwsep_est=0.00019571401752467945, cost_est=34.33651951754235)]

What I want to do is to retrieve each value of the first column (angle_est), and pass it as parameter xMisallignment to a defined function to set a particular property of a class object. The defined function is:

def setMisAllignment(self, xMisallignment):
    if np.abs(xMisallignment) > 0.8:
       warnings.warn('You might set misallignment angle too large.')
    self.MisAllignment = xMisallignment

I am trying to select the first column and convert it into rdd, and apply the above function to a map() function, but it seems it does not work, the MisAllignment did not change anyway.

df.select(df.angle_est).rdd.map(lambda row: model0.setMisAllignment(row))

In[2]: model0.MisAllignment
Out[2]: 0.00111511718224

Anyone has ideas to help me let that function work? Thanks in advance!