How to separate one column to multiple column (complex column)

I am trying to separate column "Grade" to multiple columns according to their subject and grade

    grade<-read.csv("https://raw.githubusercontent.com/tuyenhavan/Statistics/Dataset/High_school_Grade.csv",sep=";")

# Rename the column names

    names(grade)<-c("Student_ID","Name","Venue","Grade")

    head(grade)

    # Separate `Grade` into `subject` variables and coresponding `Grade`columns
    library(tidyverse)


    df<- grade %>% separate(Grade,paste("V",1:7,sep="_"),sep=":")

    head(df)

    # It still is not separating `subject ` and `grade` independently

    # Here is what I want it to look like

    new_df<-df[c(1:5),c(1:4)]

    new_df<-data.frame(new_df, V2=c(1:5)) # the same for V2,4,5,6,,7 to separate subject and grade

    new_df 

I am trying to use dplyr and stringr, but could not produce the result as I expected