How to generate a list from a pandas DataFrame with the column name and column values?

I have a pandas dataframe object that looks like this:

   one  two  three  four  five
0    1    2      3     4     5
1    1    1      1     1     1

I'd like to generate a list of lists objects where the first item is the column label and the remaining list values are the column data values:

nested_list = [['one', 1, 1]
               ['two', 2, 1]
               ['three', 3, 1]
               ['four', 4, 1]
               ['five', 5, 1]]

How can I do this? Thanks for the help.