Why are these words considered stopwords?

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I do not have a formal background in Natural Language Processing was wondering if someone from the NLP side can shed some light on this. I am playing around with the NLTK library and I was specifically looking into the stopwords function provided by this package:

In [80]: nltk.corpus.stopwords.words('english')

Out[80]:

['i', 'me', 'my', 'myself', 'we', 'our', 'ours', 'ourselves', 'you', 'your', 'yours', 'yourself', 'yourselves', 'he', 'him', 'his', 'himself', 'she', 'her', 'hers', 'herself', 'it', 'its', 'itself', 'they', 'them', 'their', 'theirs', 'themselves', 'what', 'which', 'who', 'whom', 'this', 'that', 'these', 'those', 'am', 'is', 'are', 'was', 'were', 'be', 'been', 'being', 'have', 'has', 'had', 'having', 'do', 'does', 'did', 'doing', 'a', 'an', 'the', 'and', 'but', 'if', 'or', 'because', 'as', 'until', 'while', 'of', 'at', 'by', 'for', 'with', 'about', 'against', 'between', 'into', 'through', 'during', 'before', 'after', 'above', 'below', 'to', 'from', 'up', 'down', 'in', 'out', 'on', 'off', 'over', 'under', 'again', 'further', 'then', 'once', 'here', 'there', 'when', 'where', 'why', 'how', 'all', 'any', 'both', 'each', 'few', 'more', 'most', 'other', 'some', 'such', 'no', 'nor', 'not', 'only', 'own', 'same', 'so', 'than', 'too', 'very', 's', 't', 'can', 'will', 'just', 'don', 'should', 'now']

What I don't understand is, why is the word "not" present? Isn't that necessary to determine the sentiment inside a sentence? For instance, a sentence like this:

I am not sure what the problem is.

is totally different once the stopword not is removed changing the meaning of the sentence to its opposite (I am sure what the problem is). If that is the case, is there a set of rules that I am missing on when not to use these stopwords?

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