Key value pairs using JSON

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Is there a way to handle data structures using JSON object in a way of Key/ Value pairs?
If so can some one elaborate how to access associated value object from the key

Assume that I have something like this

KEY1 |  VALUE OBJECT1 - (NAME: "XXXXXX", VALUE:100.0)  
KEY2 |  VALUE OBJECT2 - (NAME: "YYYYYYY", VALUE:200.0)  
KEY3 |  VALUE OBJECT3 - (NAME: "ZZZZZZZ", VALUE:500.0)  
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