I now develop websites and XML interfaces since 7 years, and never, ever came in a situation, where it was really necessary to use the > for a >. All disambiguition could so far be handled by quoting <, &, " and ' alone.
Has anyone ever been in a situation (related to, e.g., SGML processing, browser issues, XSLT, ...) where you found it indespensable to escape the greater-than sign with >?
Update: I just checked with the XML spec, where it says, for example, about character data in section 2.4:
Character Data
[14] CharData ::= [^<&]* - ([^<&]* ']]>' [^<&]*)
So even there, the > isn't mentioned as something special, except from the ending sequence of a CDATA section.
This one single case, where the > is of any significance, would be the ending of a CDATA section, ]]>, but then again, if you'd quote it, the quote (i.e., the literal string ]]>) would land literally in the output (since it's CDATA).