Imitate/emulate a big-endian behavior in C?

I was wondering if it's possible to emulate a big-endian behavior, for testing purpose?

via either windows or linux , mingw or gcc. Here's a sample of code which I would like the emulation to return big endian:

#include <stdio.h>
#include <stdlib.h>
#include <string.h>

#include <limits.h>
#if CHAR_BIT != 8
#error "Unsupported char size for detecting endianness"
#endif

int main (void)
{
  short int word = 0x0001;
  char *byte = (char *) &word;
  if (byte[0]) printf("little endian");
  else printf("big endian");
  return 0;
}