Cannot borrow `scores` as mutable more than once?

You can't borrow twice mutable from the same HashMap. The entry() call borrows from HashMap.

To fix this, just don't do it simultaneously. Borrow one, mutate, and then borrow the other.

// hashmaps3.rs

// A list of scores (one per line) of a soccer match is given. Each line
// is of the form :
// <team_1_name>,<team_2_name>,<team_1_goals>,<team_2_goals>
// Example: England,France,4,2 (England scored 4 goals, France 2).

// You have to build a scores table containing the name of the team, goals
// the team scored, and goals the team conceded. One approach to build
// the scores table is to use a Hashmap. The solution is partially
// written to use a Hashmap, complete it to pass the test.

// Make me pass the tests!

// Execute `rustlings hint hashmaps3` or use the `hint` watch subcommand for a hint.

// I AM NOT DONE

use std::collections::HashMap;

// A structure to store team name and its goal details.
struct Team {
    name: String,
    goals_scored: u8,
    goals_conceded: u8,
}

fn build_scores_table(results: String) -> HashMap<String, Team> {
    // The name of the team is the key and its associated struct is the value.
    let mut scores: HashMap<String, Team> = HashMap::new();

    for r in results.lines() {
        let v: Vec<&str> = r.split(',').collect();
        let team_1_name = v[0].to_string();
        let team_1_score: u8 = v[2].parse().unwrap();
        let team_2_name = v[1].to_string();
        let team_2_score: u8 = v[3].parse().unwrap();
        let team_1 = Team {
            name: team_1_name.clone(),
            goals_scored: team_1_score,
            goals_conceded: team_2_score,
        };
        let team_2 = Team {
            name: team_2_name.clone(),
            goals_scored: team_2_score,
            goals_conceded: team_1_score,
        };
        let team1 = scores.entry(team_1_name).or_insert(team_1);
        team1.goals_scored += team_1_score;
        team1.goals_conceded += team_2_score;

        let team2 = scores.entry(team_2_name).or_insert(team_2);
        team2.goals_scored += team_2_score;
        team2.goals_conceded += team_1_score;
    }
    scores
}

#[cfg(test)]
mod tests {
    use super::*;

    fn get_results() -> String {
        let results = "".to_string()
            + "England,France,4,2\n"
            + "France,Italy,3,1\n"
            + "Poland,Spain,2,0\n"
            + "Germany,England,2,1\n";
        results
    }

    #[test]
    fn build_scores() {
        let scores = build_scores_table(get_results());

        let mut keys: Vec<&String> = scores.keys().collect();
        keys.sort();
        assert_eq!(
            keys,
            vec!["England", "France", "Germany", "Italy", "Poland", "Spain"]
        );
    }

    #[test]
    fn validate_team_score_1() {
        let scores = build_scores_table(get_results());
        let team = scores.get("England").unwrap();
        assert_eq!(team.goals_scored, 5);
        assert_eq!(team.goals_conceded, 4);
    }

    #[test]
    fn validate_team_score_2() {
        let scores = build_scores_table(get_results());
        let team = scores.get("Spain").unwrap();
        assert_eq!(team.goals_scored, 0);
        assert_eq!(team.goals_conceded, 2);
    }
}

That said, there are still problems with your code. Mainly that you write the goals to the team at or_insert(), and then add them again.

If you insert, insert with an empty score, as you will add the goals later.

// hashmaps3.rs

// A list of scores (one per line) of a soccer match is given. Each line
// is of the form :
// <team_1_name>,<team_2_name>,<team_1_goals>,<team_2_goals>
// Example: England,France,4,2 (England scored 4 goals, France 2).

// You have to build a scores table containing the name of the team, goals
// the team scored, and goals the team conceded. One approach to build
// the scores table is to use a Hashmap. The solution is partially
// written to use a Hashmap, complete it to pass the test.

// Make me pass the tests!

// Execute `rustlings hint hashmaps3` or use the `hint` watch subcommand for a hint.

// I AM NOT DONE

use std::collections::HashMap;

// A structure to store team name and its goal details.
struct Team {
    name: String,
    goals_scored: u8,
    goals_conceded: u8,
}

fn build_scores_table(results: String) -> HashMap<String, Team> {
    // The name of the team is the key and its associated struct is the value.
    let mut scores: HashMap<String, Team> = HashMap::new();

    for r in results.lines() {
        let v: Vec<&str> = r.split(',').collect();
        let team_1_name = v[0].to_string();
        let team_1_score: u8 = v[2].parse().unwrap();
        let team_2_name = v[1].to_string();
        let team_2_score: u8 = v[3].parse().unwrap();
        let team_1 = Team {
            name: team_1_name.clone(),
            goals_scored: 0,
            goals_conceded: 0,
        };
        let team_2 = Team {
            name: team_2_name.clone(),
            goals_scored: 0,
            goals_conceded: 0,
        };
        let team1 = scores.entry(team_1_name).or_insert(team_1);
        team1.goals_scored += team_1_score;
        team1.goals_conceded += team_2_score;

        let team2 = scores.entry(team_2_name).or_insert(team_2);
        team2.goals_scored += team_2_score;
        team2.goals_conceded += team_1_score;
    }
    scores
}

#[cfg(test)]
mod tests {
    use super::*;

    fn get_results() -> String {
        let results = "".to_string()
            + "England,France,4,2\n"
            + "France,Italy,3,1\n"
            + "Poland,Spain,2,0\n"
            + "Germany,England,2,1\n";
        results
    }

    #[test]
    fn build_scores() {
        let scores = build_scores_table(get_results());

        let mut keys: Vec<&String> = scores.keys().collect();
        keys.sort();
        assert_eq!(
            keys,
            vec!["England", "France", "Germany", "Italy", "Poland", "Spain"]
        );
    }

    #[test]
    fn validate_team_score_1() {
        let scores = build_scores_table(get_results());
        let team = scores.get("England").unwrap();
        assert_eq!(team.goals_scored, 5);
        assert_eq!(team.goals_conceded, 4);
    }

    #[test]
    fn validate_team_score_2() {
        let scores = build_scores_table(get_results());
        let team = scores.get("Spain").unwrap();
        assert_eq!(team.goals_scored, 0);
        assert_eq!(team.goals_conceded, 2);
    }
}

Further, you can extract the creation of a new team with empty scores into a separate function. This makes your code a lot cleaner. Further, you can use .or_insert_with() to run the initialization code only when needed.

// hashmaps3.rs

// A list of scores (one per line) of a soccer match is given. Each line
// is of the form :
// <team_1_name>,<team_2_name>,<team_1_goals>,<team_2_goals>
// Example: England,France,4,2 (England scored 4 goals, France 2).

// You have to build a scores table containing the name of the team, goals
// the team scored, and goals the team conceded. One approach to build
// the scores table is to use a Hashmap. The solution is partially
// written to use a Hashmap, complete it to pass the test.

// Make me pass the tests!

// Execute `rustlings hint hashmaps3` or use the `hint` watch subcommand for a hint.

// I AM NOT DONE

use std::collections::HashMap;

// A structure to store team name and its goal details.
struct Team {
    name: String,
    goals_scored: u8,
    goals_conceded: u8,
}

impl Team {
    fn new(name: &str) -> Self {
        Self {
            name: name.to_string(),
            goals_scored: 0,
            goals_conceded: 0,
        }
    }
}

fn build_scores_table(results: String) -> HashMap<String, Team> {
    // The name of the team is the key and its associated struct is the value.
    let mut scores: HashMap<String, Team> = HashMap::new();

    for r in results.lines() {
        let v: Vec<&str> = r.split(',').collect();
        let team_1_name = v[0].to_string();
        let team_1_score: u8 = v[2].parse().unwrap();
        let team_2_name = v[1].to_string();
        let team_2_score: u8 = v[3].parse().unwrap();

        let team1 = scores
            .entry(team_1_name.clone())
            .or_insert_with(|| Team::new(&team_1_name));
        team1.goals_scored += team_1_score;
        team1.goals_conceded += team_2_score;

        let team2 = scores
            .entry(team_2_name.clone())
            .or_insert_with(|| Team::new(&team_2_name));
        team2.goals_scored += team_2_score;
        team2.goals_conceded += team_1_score;
    }
    scores
}

#[cfg(test)]
mod tests {
    use super::*;

    fn get_results() -> String {
        let results = "".to_string()
            + "England,France,4,2\n"
            + "France,Italy,3,1\n"
            + "Poland,Spain,2,0\n"
            + "Germany,England,2,1\n";
        results
    }

    #[test]
    fn build_scores() {
        let scores = build_scores_table(get_results());

        let mut keys: Vec<&String> = scores.keys().collect();
        keys.sort();
        assert_eq!(
            keys,
            vec!["England", "France", "Germany", "Italy", "Poland", "Spain"]
        );
    }

    #[test]
    fn validate_team_score_1() {
        let scores = build_scores_table(get_results());
        let team = scores.get("England").unwrap();
        assert_eq!(team.goals_scored, 5);
        assert_eq!(team.goals_conceded, 4);
    }

    #[test]
    fn validate_team_score_2() {
        let scores = build_scores_table(get_results());
        let team = scores.get("Spain").unwrap();
        assert_eq!(team.goals_scored, 0);
        assert_eq!(team.goals_conceded, 2);
    }
}