SSL validation failed for https://iam.amazonaws.com/ [Errno 2] No such file or directory in Windows 10

In Windows-10 Command Prompt, I am keep on getting this error message while I type simple command: aws iam list-users after aws configure.

Even tried below options

copy "C:\Program Files\Amazon\AWSCLIV2\awscli\botocore\cacert.pem" "c:\Program Files\Amazon\AWSCLI\cacert.pem"

But it didnt work for me. Please help here.