Here is an improved version of my previous answer :
library(pagedown)
library(pdftools)
library(stringr)
chrome_print(input = "https://apps.fas.usda.gov/export-sales/corn.htm",
output = "C:\\stackoverflow101.pdf")
text <- pdftools::pdf_text("C:\\stackoverflow101.pdf")
text <- unlist(strsplit(text, "\r\n|\n"))
text <- text[-(1 : 10)]
text <- text[-44]
text <- text[text != " :"]
text <- text[text != "--------------------------------------------------------------------------------"]
regex <- "(.*:)|([:space:]*(\\d{1,4}\\.\\d{1}|\\*|-))"
list_Numbers <- stringr::str_extract_all(text, pattern = regex)
mat_Numbers <- do.call("rbind", list_Numbers)
mat_Numbers
[,1] [,2] [,3] [,4] [,5] [,6] [,7]
[1,] "EUROPEAN UNION - 27 :" " 105.2" " 0.1" " *" " *" " 0.0" " 0.0"
[2,] " ITALY :" " 105.0" " 0.0" " 0.0" " 0.0" " 0.0" " 0.0"
[3,] " U KING :" " 0.2" " 0.1" " *" " *" " 0.0" " 0.0"
[4,] "JAPAN :" " 908.8" " 1686.5" " *" " *" " 0.0" " 0.0"
[5,] "TAIWAN :" " 89.3" " 153.5" " 3.9" " 1.0" " 0.0" " 0.0"
[6,] "CHINA :" " 3223.4" "1901.2" " 137.1" " 0.0" " 0.0" " 0.0"
[7,] "OTHER ASIA AND OCEANIA:" " 40.3" " 72.8" " 0.1" " 0.4" " 0.0" " 0.0"
[8,] " HG KONG :" " 0.1" " 1.1" " *" " 0.2" " 0.0" " 0.0"
[9,] " KOR REP :" " 6.6" " 71.5" " 0.1" " 0.2" " 0.0" " 0.0"
[10,] " MALAYSA :" " 1.0" " 0.0" " 0.0" " 0.0" " 0.0" " 0.0"
[11,] " PHIL :" " 2.7" " 0.2" " 0.0" " 0.0" " 0.0" " 0.0"
[12,] " QATAR :" " 0.0" " 0.0" " *" " 0.0" " 0.0" " 0.0"
[13,] " S ARAB :" " 30.0" " 0.0" " 0.0" " 0.0" " 0.0" " 0.0"
[14,] "WESTERN HEMISPHERE :" " 5975.7" " 7991.2" " 322.5" " 358.4" " 90.5" " 0.0"
[15,] " BARBADO :" " 8.0" " 6.3" " 4.4" " 0.0" " 0.0" " 0.0"
[16,] " C RICA :" " 214.3" " 349.8" " 0.0" " 0.0" " 0.0" " 0.0"
[17,] " CANADA :" " 35.6" " 556.0" " 1.9" " 33.6" " 0.0" " 0.0"
[18,] " COLOMB :" " 182.0" " 854.2" " 10.8" " 0.0" " 0.0" " 0.0"
[19,] " DOM REP :" " 33.0" " 35.8" " 0.0" " 0.0" " 0.0" " 0.0"
[20,] " GUATMAL :" " 291.1" " 433.7" " 0.0" " 0.0" " 0.0" " 0.0"
[21,] " HAITI :" " 0.0" " 2.3" " 0.0" " 0.0" " 0.0" " 0.0"
[22,] " HONDURA :" " 196.4" " 214.8" " 71.1" " 0.0" " 0.0" " 0.0"
[23,] " JAMAICA :" " 53.6" " 82.9" " 2.8" " 0.0" " 0.0" " 0.0"
[24,] " LW WW I :" " 1.5" " 4.7" " 0.9" " 0.0" " 0.0" " 0.0"
[25,] " MEXICO :" " 4723.2" " 4929.2" " 190.8" " 317.6" " 90.5" " 0.0"
[26,] " NICARAG :" " 0.0" " 128.7" " 18.9" " 0.0" " 0.0" " 0.0"
[27,] " PANAMA :" " 93.3" " 245.5" " 5.6" " 0.0" " 0.0" " 0.0"
[28,] " SALVADR :" " 129.4" " 120.0" " 15.4" " 7.2" " 0.0" " 0.0"
[29,] " TRINID :" " 0.0" " 15.4" " 0.0" " 0.0" " 0.0" " 0.0"
[30,] " VENEZ :" " 14.5" " 12.0" " 0.0" " 0.0" " 0.0" " 0.0"
[31,] "TOTAL KNOWN :" "0342.7" "1805.3" " 463.6" " 359.9" " 90.5" " 0.0"
[32,] "TOTAL UNKNOWN :" " 1494.9" " 2407.5" " 0.0" " 0.0" " 0.0" " 0.0"
[33,] "TOTAL KNOWN & UNKNOWN :" "1837.7" "4212.8" " 463.6" " 359.9" " 90.5" " 0.0"
[34,] "EXPORTS FOR OWN ACCT :" " -" " -" " 0.0" " 0.0" " -" " -"
[35,] "OPTIONAL ORIGIN :" " 0.0" " 170.0" " -" " -" " 0.0" " 0.0"