I am storing dictionaries in my session referenced by a string key:
>>> request.session['my_dict'] = {'a': 1, 'b': 2, 'c': 3}
The problem I encountered was that when I modified the dictionary directly, the value would not be changed during the next request:
>>> request.session['my_dict'].pop('c')
3
>>> request.session.has_key('c')
False
# looks okay...
...
# Next request
>>> request.session.has_key('c')
True
# what gives!