Clustered Index
A Clustered Index is basically a tree-organized table. Instead of storing the records in an unsorted Heap table space, the clustered index is actually B+Tree index having the Leaf Nodes, which are ordered by the clusters key column value, store the actual table records, as illustrated by the following diagram.

The Clustered Index is the default table structure in SQL Server and MySQL. While MySQL adds a hidden clusters index even if a table doesn't have a Primary Key, SQL Server always builds a Clustered Index if a table has a Primary Key column. Otherwise, the SQL Server is stored as a Heap Table.
The Clustered Index can speed up queries that filter records by the clustered index key, like the usual CRUD statements. Since the records are located in the Leaf Nodes, there's no additional lookup for extra column values when locating records by their Primary Key values.
For example, when executing the following SQL query on SQL Server:
SELECT PostId, Title
FROM Post
WHERE PostId = ?
You can see that the Execution Plan uses a Clustered Index Seek operation to locate the Leaf Node containing the Post record, and there are only two logical reads required to scan the Clustered Index nodes:
|StmtText |
|-------------------------------------------------------------------------------------|
|SELECT PostId, Title FROM Post WHERE PostId = @P0 |
| |--Clustered Index Seek(OBJECT:([high_performance_sql].[dbo].[Post].[PK_Post_Id]), |
| SEEK:([high_performance_sql].[dbo].[Post].[PostID]=[@P0]) ORDERED FORWARD) |
Table 'Post'. Scan count 0, logical reads 2, physical reads 0
Non-Clustered Index
Since the Clustered Index is usually built using the Primary Key column values, if you want to speed up queries that use some other column, then you'll have to add a Secondary Non-Clustered Index.
The Secondary Index is going to store the Primary Key value in its Leaf Nodes, as illustrated by the following diagram:

So, if we create a Secondary Index on the Title column of the Post table:
CREATE INDEX IDX_Post_Title on Post (Title)
And we execute the following SQL query:
SELECT PostId, Title
FROM Post
WHERE Title = ?
We can see that an Index Seek operation is used to locate the Leaf Node in the IDX_Post_Title index that can provide the SQL query projection we are interested in:
|StmtText |
|------------------------------------------------------------------------------|
|SELECT PostId, Title FROM Post WHERE Title = @P0 |
| |--Index Seek(OBJECT:([high_performance_sql].[dbo].[Post].[IDX_Post_Title]),|
| SEEK:([high_performance_sql].[dbo].[Post].[Title]=[@P0]) ORDERED FORWARD)|
Table 'Post'. Scan count 1, logical reads 2, physical reads 0
Since the associated PostId Primary Key column value is stored in the IDX_Post_Title Leaf Node, this query doesn't need an extra lookup to locate the Post row in the Clustered Index.