git mv moves the file, updating the index to record the replaced file path, as well as updating any affected git submodules. Unlike a manual move, it also detects case-only renames that would not otherwise be detected as a change by git.
It is similar (though not identical) in behavior to moving the file externally to git, removing the old path from the index using git rm, and adding the new one to the index using git add.
Answer Motivation
This question has a lot of great partial answers. This answer is an attempt to combine them into a single cohesive answer. Additionally, one thing not called out by any of the other answers is the fact that the man page actually does mostly answer the question, but it's perhaps less obvious than it could be.
Detailed Explanation
Three different effects are called out in the man page:
The file, directory, or symlink is moved in the filesystem:
git-mv - Move or rename a file, a directory, or a symlink
The index is updated, adding the new path and removing the previous one:
The index is updated after successful completion, but the change must still be committed.
Moved submodules are updated to work at the new location:
Moving a submodule using a gitfile (which means they were cloned with a Git version 1.7.8 or newer) will update the gitfile and core.worktree setting to make the submodule work in the new location. It also will attempt to update the submodule.<name>.path setting in the gitmodules(5) file and stage that file (unless -n is used).
As mentioned in this answer, git mv is very similar to moving the file, adding the new path to the index, and removing the previous path from the index:
mv oldname newname
git add newname
git rm oldname
However, as this answer points out, git mv is not strictly identical to this in behavior. Moving the file via git mv adds the new path to the index, but not any modified content in the file. Using the three individual commands, on the other hand, adds the entire file to the index, including any modified content. This could be relevant when using a workflow which patches the index, rather than adding all changes in the file.
Additionally, as mentioned in this answer and this comment, git mv has the added benefit of handling case-only renames on file systems that are case-insensitive but case-preserving, as is often the case in current macOS and Windows file systems. For example, in such systems, git would not detect that the file name has changed after moving a file via mv Mytest.txt MyTest.txt, whereas using git mv Mytest.txt MyTest.txt would successfully update its name.