Want to seperate string every 2 new lines and add it to array

There are several ways to do this. Here is one using the Scanner class to read the file line by line. The strategy used in this example is to discard the first line and then use a while loop to iterate over the rest of the file.

This example assumes the file exists in the resources since the OP appears to be loading a resource file.

public List<String> extractPeople(String fileName) throws IOException, URISyntaxException {

    List<String> people = new ArrayList<>();
    
    URL url = getClass().getClassLoader().getResource(fileName);
    if (Objects.isNull(url)) throw new IOException("Unable to load URL for file: " + fileName);
    
    // try with resources and use scanner to read file one line a time
    try (Scanner scanner = new Scanner(new FileReader(new File(url.toURI())))) {
        
        // move cursor to the second line
        if(scanner.hasNextLine()) scanner.nextLine();
        
        // loop through the file
        while(scanner.hasNextLine()) {
            
            // extract the line with name
            String name = scanner.nextLine();
            
            // extract the line with the age
            String age = scanner.nextLine();
            
            // concatenate name and age and add to list of results.
            people.add(name.concat(age));
        }
    }
    
    return people;
}

And a simple test using a text file named "people.txt" based of the question.

@Test
void shouldLoadPeople() throws IOException, URISyntaxException {
    List<String> people = extractPeople("people.txt");
    assertEquals(5, people.size());
}

Just another way. As it does indeed appear that the file to read is located within a resources directory, the following runnable code will read the file in both the IDE or the distributive JAR file. The resources directory is assumed to be located within the following hierarchy:

ProjectFolder
   src
       resources
           Users.txt

Read the comments in code:

public class ExtractDataDemo {
    
    private final String LS = System.lineSeparator();
    
    // Class global List to hold read in Users.
    private final java.util.List<String> usersList = new java.util.ArrayList<>();
    private final String resourceFile = "/resources/Users.txt";
    
    
    public static void main(String[] args) {
        // Started this way to avoid the need for statics.
        new ExtractDataDemo().startApp(args);
    }

    private void startApp(String[] args) {
        try {
            // Read the Users.txt file
            readUsers(resourceFile);
        }
        catch (java.io.IOException ex) {
            // Display IO exceptions (if any) in Console.
            System.err.println(ex);
            return;
        }
        
        // Make sure the Users List contains something.
        if (usersList.isEmpty()) {
            System.out.println("No Users To List!");
            return
        }

        // Display the people List contents in Console Window:
        System.out.println(LS + "Users List (as List):");
        System.out.println("=====================");
        for (String elements : usersList) {
            System.out.println(elements);
        }        
        System.out.println();
                
        // Display a table style formated people List in Console:
        // Header...
        System.out.println("Users List (as Table):");
        System.out.println("======================");
        System.out.printf("%-8s %-11s %-3s%n", "Import", "Name", "Age");
        System.out.println("------------------------");
        
        // Iterate through the people List so to format contents...
        for (String peeps : usersList) {
            // Split list element into parts for formatting.
            String[] peepParts = peeps.split("/");
            System.out.printf("  %-6s %-11s %-3s%n", 
                              peepParts[0],                        // Import Number
                              peepParts[1].split("\\s*=\\s*")[1],  // Name 
                              peepParts[2].split("\\s*=\\s*")[1]); // Age
        }
        System.out.println("------------------------");
        System.out.println(LS + "< DONE >" + LS);
        // DONE
    }

    public void readUsers(String fileName) throws IOException {
        /* Clear the usersList in case it has something 
           already in it from a previous operation:  */
        usersList.clear();
        
        /* Read from resources directory. This will work in
        both the IDE and a distributive JAR file. 'Try With
        Resources' is used here to auto-close file and free
        resources.                                       */
        try (java.io.InputStream in = getClass().getResourceAsStream(fileName)) {
            if (in == null) {
                throw new IOException("Unable To Locate Resource! (" + fileName + ")");
            }
            try (java.io.BufferedReader reader = new java.io.BufferedReader(new java.io.InputStreamReader(in))) {
                String line;
                //Skip header line in file (don't want it this time).
                line = reader.readLine();

                while ((line = reader.readLine()) != null) {
                    // Get Import # from line (ex: "1"/name=Arwin)
                    String imprt = line.split("/")[0];

                    // Get Name from line (ex: 1/"name=Arwin")
                    String name = line.split("/")[1];

                    /* Read in the line with the age (omit the line number)
                    [Ex: "2/Age=22"]         */
                    line = reader.readLine();

                    // Get the age from line (ex: 2/"Age=22")
                    String age = line.split("/")[1];

                    // Concatenate import number, name, and age then add to usersList.
                    usersList.add(imprt.concat("/").concat(name).concat("/").concat(age));
                }
            }
        }
    }
}

When the code above is run, the following is what should be displayed within the Console Window providing the Users.txt file can be found:

Users List (as List):
=====================
1/name=Arwin/Age=22
3/name=AJ/Age = 27
5/name=Anna/Age = 21
7/name=Avon/Age = 25
9/name=Atman/Age = 19

Users List (as Table):
======================
Import   Name        Age
------------------------
  1      Arwin       22 
  3      AJ          27 
  5      Anna        21 
  7      Avon        25 
  9      Atman       19 
------------------------

< DONE >